Smooth AF Tonic

Fourth Ray Beauty

Where to buy Possibly in stock

About this product

The Fourth Ray Beauty Smooth AF Tonic is a toner. Our analysis of its 31 ingredients (20 low-risk) rates it Excellent (96/100).

Vegan-friendly Reef-safe

Summarised from our ingredient analysis — not brand marketing copy.

At a glance

Type
Toners
Ingredients
31
Low-risk
20
Fragrance
Fragrance-free
Origin
United States

The evidence

Quick Product Notes

Paraben-Free Sulfate-Free Alcohol-Free Silicone-Free EU Allergen-Free Fungal Acne (Malassezia) Safe

Notable Effects & Ingredients

No Notable Effects & Ingredients

Ingredients Related to Skin Types

Good   Bad — tap a skin type to see which ingredients · estimated from ingredient functions
Dry Skin 4/5
Good for dry skin
Caprylic/Capric Triglyceride Caprylyl Glycol Glycerin Lactic Acid
Caution for dry skin
Glycerin Hexylene Glycol Sodium Hydroxide Polysorbate 20 PEG-40 Hydrogenated Castor Oil
Oily/Acne-Prone Skin No data
Sensitive Skin 1/9
Good for sensitive skin
Glycerin
Caution for sensitive skin
Calendula Officinalis Flower Extract Caprylic/Capric Triglyceride Glycerin Hexylene Glycol Citric Acid Potassium Sorbate PEG-40 Hydrogenated Castor Oil Lactic Acid Phenoxyethanol

Ingredients list

31 total
Lower hazard (1) Higher hazard (4)
All31 Skin Conditioning20 Perfuming7 Fragrance7 Solvent6 Humectant4 Ph Adjuster4 Buffering Agent4 Hair Conditioning4
EWG CIR Ingredient Name & Cosmetic Functions Notes
1
Water
(Solvent)
4
B
Lactic Acid
(Exfoliant, Fragrance, Humectant, Ph Adjuster, Skin Conditioning Agent Humectant, Skin Conditioning, Buffering Agent)
Bad for Sensitive Skin
Bad for Sensitive Skin
1
Propanediol
(Solvent, Viscosity Decreasing Agent, Viscosity Controlling)
3
B
Sodium Hydroxide
(Denaturant, Ph Adjuster, Buffering Agent)
4
B
Glycolic Acid
(Exfoliant, Ph Adjuster, Buffering Agent)
Good for Oily Skin
Good for Oily Skin
Bad for Sensitive Skin
Bad for Sensitive Skin
2
A
Citric Acid
(Chelating Agent, Fragrance, Ph Adjuster, Buffering Agent, Masking)
Bad for Sensitive Skin
Bad for Sensitive Skin
3
A
PEG-12 Dimethicone
(Hair Conditioning, Skin Conditioning)
1
A
Pentylene Glycol
(Skin Conditioning, Solvent)
3
B
Polysorbate 20
(Emulsifying, Surfactant)
Fungal Acne
Fungal Acne Trigger
Citrus Aurantium Dulcis Peel Extract
(Binding, Emulsion Stabilising, Perfuming, Skin Conditioning, Viscosity Controlling)
Citrus Paradisi Fruit Extract
(Skin Conditioning)
1
A
Calendula Officinalis Flower Extract
(Masking, Perfuming, Skin Conditioning)
Citrus Clementina Fruit Extract
(Skin Conditioning)
citrus limon peel extract
(Skin Conditioning, Skin Conditioning Emollient, Skin Protecting, Tonic)
Citrus Tangerina Peel Extract
(Astringent)
Punica Granatum Fruit Extract
(Skin Conditioning)
Pyrus Malus Fruit Extract
(Skin Conditioning)
glycyrrhiza glabra root extract
(Bleaching, Perfuming, Skin Conditioning, Skin Conditioning Emollient, Smoothing, Soothing)
1
Lactobacillus/Papaya Fruit Ferment Extract
(Abrasive, Hair Conditioning, Skin Conditioning)
1
Leuconostoc/Radish Root Ferment Filtrate
(Antidandruff Agent, Antimicrobial)
3
B
PEG-40 Hydrogenated Castor Oil
(Fragrance, Emulsifying, Surfactant, Perfuming)
Fungal Acne
Fungal Acne Trigger
1
A
Caprylyl Glycol
(Hair Conditioning, Skin Conditioning, Emollient, Humectant)
2
A
Glycerin
(Denaturant, Fragrance, Hair Conditioning, Humectant, Oral Care Agent, Oral Health Care Drug, Skin Protecting, Viscosity Decreasing Agent, Perfuming, Solvent)
Good for Dry Skin
Good for Dry Skin
Fungal Acne
Fungal Acne Trigger
1
A
Caprylic/Capric Triglyceride
(Emollient, Masking, Perfuming, Skin Conditioning, Solvent)
1
A
Hexylene Glycol
(Fragrance, Solvent, Viscosity Decreasing Agent, Emulsifying, Perfuming, Skin Conditioning, Surfactant)
1
A
Ethylhexylglycerin
(Deodorant, Skin Conditioning)
1
A
Trisodium EDTA
(Chelating Agent)
1
A
Cetyl Hydroxyethylcellulose
(Emulsion Stabilising, Viscosity Increasing Agent, Film Forming, Viscosity Controlling)
3
A
Potassium Sorbate
(Fragrance, Preservative)
4
A
Phenoxyethanol
(Fragrance, Preservative)
Paraben
Paraben
3
CI 16035
(Cosmetic Colorant)

My Ingredient Notes

No personal ingredient notes yet. Save ingredients to your profile to get good/bad alerts here.

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Key ingredients

AHA
Exfoliates skin for a brighter complexion.
Exfoliators
Removes dead skin cells to smoothe texture.
Antioxidants
Shields skin from free radical damage.

Benefits

HydratingBoosts hydration and relieves dry, tight skin.
Barrier RepairStrengthen and restore your skin's natural barrier.
BrighteningRestores radiance to dull, tired skin.
Scar HealingImproves the look of marks and scars.
Dark SpotsFades dark spots for even skin tone.
Reduces IrritationEases discomfort and supports skin resilience.
Anti-AgingSoftens lines and helps skin look youthful.
Good For Oily SkinBalances oil and helps reduce shine.

Concerns

Contains paraben
Not fungal acne (malassezia) safe
May not suit dry skin
May not suit sensitive skin

Ingredients explained

Water
Solvent
Low-hazard ingredient.Read moreShow less
EWG 1 Solvent
Propanediol
Solvent, Viscosity decreasing agent
Low-hazard ingredient.Read moreShow less
EWG 1 SolventViscosity decreasing agentViscosity controlling
Sodium Hydroxide
Denaturant, Ph adjuster
Low-to-moderate hazard.Read moreShow less
EWG 3 CIR B DenaturantPh adjusterBuffering agent
PEG-12 Dimethicone
Hair conditioning, Skin conditioning
Low-to-moderate hazard.Read moreShow less
EWG 3 CIR A Hair conditioningSkin conditioning
Pentylene Glycol
Skin conditioning, Solvent
Low-hazard ingredient.Read moreShow less
EWG 1 CIR A Skin conditioningSolvent
Citrus Aurantium Dulcis Peel Extract
Binding, Emulsion stabilising
Limited public safety data.Read moreShow less
EWG N/A BindingEmulsion stabilisingPerfumingSkin conditioningViscosity controlling
Citrus Paradisi Fruit Extract
Skin conditioning
Limited public safety data.Read moreShow less
EWG N/A Skin conditioning
Calendula Officinalis Flower Extract
Masking, Perfuming
Low-hazard ingredient.Read moreShow less
EWG 1 CIR A MaskingPerfumingSkin conditioning
Citrus Clementina Fruit Extract
Skin conditioning
Limited public safety data.Read moreShow less
EWG N/A Skin conditioning
citrus limon peel extract
Skin conditioning, Skin conditioning emollient
Limited public safety data.Read moreShow less
EWG N/A Skin conditioningSkin conditioning emollientSkin protectingTonic
Citrus Tangerina Peel Extract
Astringent
Limited public safety data.Read moreShow less
EWG N/A Astringent
Punica Granatum Fruit Extract
Skin conditioning
Limited public safety data.Read moreShow less
EWG N/A Skin conditioning
Pyrus Malus Fruit Extract
Skin conditioning
Limited public safety data.Read moreShow less
EWG N/A Skin conditioning
glycyrrhiza glabra root extract
Bleaching, Perfuming
Limited public safety data.Read moreShow less
EWG N/A BleachingPerfumingSkin conditioningSkin conditioning emollientSmoothingSoothing
Lactobacillus/Papaya Fruit Ferment Extract
Abrasive, Hair conditioning
Low-hazard ingredient.Read moreShow less
EWG 1 AbrasiveHair conditioningSkin conditioning
+ 9 more — see the full ingredients list above
Lactic Acid
Exfoliant, Fragrance
Skin irritation can occur at high concentrationRead moreShow less
EWG 4 CIR B ExfoliantFragranceHumectantPh adjusterSkin-conditioning agent -humectantSkin conditioningBuffering agent Bad for Sensitive Skin
Glycolic Acid
Exfoliant, Ph adjuster
Skin irritation can occur at high concentrationRead moreShow less
EWG 4 CIR B ExfoliantPh adjusterBuffering agent Good for Oily SkinBad for Sensitive Skin
Citric Acid
Chelating agent, Fragrance
Skin irritation can occur at high concentrationRead moreShow less
EWG 2 CIR A Chelating agentFragrancePh adjusterBuffering agentMasking Bad for Sensitive Skin
Polysorbate 20
Emulsifying, Surfactant
Low-to-moderate hazard.Read moreShow less
EWG 3 CIR B EmulsifyingSurfactant Fungal-acne trigger
PEG-40 Hydrogenated Castor Oil
Fragrance, Emulsifying
Low-to-moderate hazard.Read moreShow less
EWG 3 CIR B FragranceEmulsifyingSurfactantPerfuming Fungal-acne trigger
Glycerin
Denaturant, Fragrance
Low-hazard ingredient.Read moreShow less
EWG 2 CIR A DenaturantFragranceHair conditioningHumectantOral care agentOral health care drugSkin protectingViscosity decreasing agentPerfumingSolvent Good for Dry SkinFungal-acne trigger
Phenoxyethanol
Fragrance, Preservative
Low-to-moderate hazard.Read moreShow less
EWG 4 CIR A FragrancePreservative Paraben

How to use

How to use

  • 1 Where it fits: Use right after cleansing, before serums.
  • 2 Evening, start slow: Best in the PM a few times a week to begin with; avoid layering with other strong actives the same night.
  • 3 Wear SPF the next day: Acids and retinoids increase sun sensitivity — daily sunscreen is a must while using this.

General guidance from this product's category and active ingredients — always follow the directions on the package.

Trust & honesty

Effective levels — general guide

The concentrations these actives are typically effective at in research — not a measurement of this product.

AHA (acid exfoliant) 5–10% (OTC)

OTC leave-on AHAs are usually 5–10%. The effect also depends on pH and free-acid value, not the percentage alone.

Lactic Acid, Glycolic Acid

INCI lists don't disclose amounts, and we don't claim to know this product's levels — these are the ranges these ingredients are usually effective at, so you can tell a real formula from "fairy-dusting" a marketed active. How we estimate this.

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